Publications

Prior to 2011

For publications prior to 2011, please use the following resources:

  • Google Scholar — fairly accurate and includes patents.
  • ResearchGate — missing ASAPs but otherwise up-to-date. Does not include patents.
  • ResearcherID — for publications through 2011. May not be comprehensive.

If you have access, SciFinder is the most thorough and complete resource.

2011-Current

168. A Scalable and Continuous Access to Pure Cyclic Polymers Enabled by Quarantined Heterogeneous Catalysts
Yoon, K.-Y.; Noh, J.; Gan, Q.; Edwards, J.; Tuba, R.; Choi, T.-L.; Grubbs, R. H.
ChemRxiv 2021.

167. Bulky Cyclometalated Ruthenium Nitrates for Challenging Z-Selective Metathesis: Efficient One-Step Access to α-Oxygenated Z-Olefins from Acrylates and Allyl Alcohols
Xu, Y.; Gan, Q.; Samkian, A. E.; Ko, J. H.; Grubbs, R. H.
Angew. Chem. Int. Ed. 2021.

166. Processing Effects on the Self-Assembly of Brush Block Polymer Photonic Crystals
Liberman-Martin, A. L.; Chang, A. B.; Chu, C. K.; Siddique, R. H.; Lee, B.; Grubbs, R. H.
ACS Macro Lett. 2021.

165. Selective CO2 Electrochemical Reduction Enabled by a Tricomponent Copolymer Modifier on a Copper Surface
Wang, J.; Cheng, T.; Fenwick, A. Q.; Baroud, T. N.; Rosas-Hernández, A.; Ko, J. H.; Gan, Q.;Goddard III, W. A.; Grubbs, R. H.
J. Am. Chem. Soc. 2021.

164. Efficient Z-Selective Olefin-Acrylamide Cross-Metathesis Enabled by Sterically Demanding Cyclometalated Ruthenium Catalysts
Xu, Y.; Wong, J. J.; Samkian, A. E.; Ko, J. H.; Chen, S.; Houk, K. N.; Grubbs, R. H.
J. Am. Chem. Soc. 2020.

163. Assessment of a Siloxane Poly(Urethane-Urea) Elastomer Designed for Implantable Heart Valve Leaflets
Jenney, C.; Millson, P.; Grainger, D. W.; Grubbs, R.; Gunatillake, P.; McCarthy, S. J.; Runt, J.; Beith, J.
Adv. NanoBiomed Res. 2020.

162. Aldehyde-Functionalized Magnetic Particles to Capture Off-Target Chemotherapeutic Agents
Krishnamoorthy, S.; Grubbs, R. H.
ACS Omega 2020.

161. Insights into the Nature of Self-Extinguishing External Donors for Ziegler-Natta Catalysis: A Combined Experimental and DFT Study
Raj, K. V.; Kumawat, J.; Dhamaniya, S.; Subaramanian, M.; Balaraman, E.; Gupta, V. K.; Vanka, K.; Grubbs, R. H.
ChemCatChem 2020.

160. Surgery-Guided Removal of Ovarian Cancer Using Up-Converting Nanoparticles
Marotta, C. B.; Haber, T.; Berlin, J. M.; Grubbs, R. H.
ACS Appl. Mater. Interfaces 2020.

159. Efficient Synthesis of Geminal-Dialkyl Dienes for Olefin Metathesis Polymerization
Wolf, W. J.; Li, J.; Jones, S. C.; Stoltz, B. M.; Grubbs, R. H.
Macromolecules 2020.

158. Concentration Dependence of the Size and Symmetry of a Bottlebrush Polymer in a Good Solvent
Sunday, D. F.; Chremos, A.; Martin, T. B.; Chang, A. B.; Burns, A. B.; Grubbs, R. H.
Macromolecules 2020.

157. Synthesis and Characterization of 3,5-Bis(Di-Tert-Butylphosphinito)Pyridine Pincer Complexes
Swisher, N. A.; Grubbs, R. H.
Organometallics 2020.

156. Electronic Structures, Spectroscopy, and Electrochemistry of [M(diimine)(CN-BR3)4]2– (M = Fe, Ru; R = Ph, C6F5) Complexes
Ngo, D. X.; Del Ciello, S. A.; Barth, A. T.; Hadt, R. G.; Grubbs, R. H.; Gray, H. B.; McNicholas, B. J.
Inorganic Chemistry 2020.

155. Ru-Catalyzed, Cis-Selective Living Ring-Opening Metathesis Polymerization of Various Monomers, Including a Dendronized Macromonomer, and Implications to Enhanced Shear Stability
Song, J.-A.; Peterson, G. I.; Bang, K.-T.; Ahmed, T. S.; Sung, J.-C.; Grubbs, R. H.; Choi, T.-L.
J. Am. Chem. Soc. 2020.

154. Aqueous Electrocatalytic CO2 Reduction Using Metal Complexes Dispersed in Polymer Ion Gels
Sato, S.; McNicholas, B. J.; Grubbs, R. H.
Chem. Commun. 2020.

153. Synthesis and Activity of Six-Membered Cyclic Alkyl Amino Carbene–Ruthenium Olefin Metathesis Catalysts
Samkian, A.E.; Xu, Y.; Virgil, S.C; Yoon, K-Y.; Grubbs, R.H.
Organometallics 2020.

152. Addressing the Challenges of Modeling the Scattering from Bottlebrush Polymers in Solution
Sunday, D.F.; Martin, T.B.; Chang, A.B.; Burns, A.B.; Grubbs, R.H.
Journal of Polymer Science 2020.

151. Enantioselective Synthesis of 15-Deoxy-Δ12,14-Prostaglandin J2
Li, J.; Stoltz, B. M.; Grubbs, R. H.
Org. Lett. 2019.

150. Examining the Effects of Monomer and Catalyst Structure on the Mechanism of Ruthenium-Catalyzed Ring-Opening Metathesis Polymerization
Wolf, W. J.; Lin, T.-P.; Grubbs, R. H.
J. Am. Chem. Soc. 2019.

149. Fluoride-Ion Solvation in Non-Aqueous Electrolyte Solutions
Davis, V. K.; Munoz, S.; Kim, J.; Bates, C. M.; Momčilović, N.; Billings, K. J.; Miller, T. F.; Grubbs, R. H.; Jones, S. C.
Mater. Chem. Front. 2019.

148. Living β-selective Cyclopolymerization Using Ru Dithiolate Catalysts
Jung, K.; Ahmed, T.S.; Lee, J.; Sung, J-C.; Keum, H.; Grubbs, R.H; Choi, T-L.
Chemical Science 2019.

147. Linear Rheology of a Series of Second-Generation Dendronized Wedge Polymers
Qian, Z.; Koh, Y.P.; Pallaka, M.R.; Chang, A.B.; Lin, T-P.; Guzmán, P.E.; Grubbs, R.H.; Simon, S.L.; McKenna, G.B.
Macromolecules 2019, 52 (5), 2063–2074.

146. Living Polymerization Caught in the Act: Direct Observation of an Arrested Intermediate in Metathesis Polymerization
Song, J-A; Park, B.; Kim, S.; Kang, C.; Lee, D.; Baik, M-H; Grubbs, R.H.; Choi, T-L.
J. Am. Chem. Soc. 2019, 141 (25), 10039–10047.

145. Tuning the formal potential of ferrocyanide over a 2.1 V range
Mcnicholas, B. J.; Grubbs, R. H.; Winkler, J. R.; Gray, H. B.; Despagnet-Ayoub, E.
Chemical Science 2019.

144. Concise Syntheses of Δ12-Prostaglandin J Natural Products via Stereoretentive Metathesis
Li, J.; Ahmed, T. S.; Xu, C.; Stoltz, B. M.; Grubbs, R. H.
J. Am. Chem. Soc. 2018, 141 (1), 154–158.

143. Highly Active Platinum Catalysts for Nitrile and Cyanohydrin Hydration: Catalyst Design and Ligand Screening via High-Throughput Techniques
Xing, X.; Xu, C.; Chen, B.; Li, C.; Virgil, S. C.; Grubbs, R. H.
J. Am. Chem. Soc. 2018, 140 (50), 17782–17789.

142. The Synthesis of Cyclic Polymers by Olefin Metathesis: Achievements and Challenges
Edwards, J. P.; Wolf, W. J.; Grubbs, R. H.
J. Polym. Sci., Part A: Polym. Chem. 2018, 57 (3), 228–242.

141. Drug Capture Materials Based on Genomic DNA-Functionalized Magnetic Nanoparticles
Blumenfeld, C. M.; Schulz, M. D.; Aboian, M. S.; Wilson, M. W.; Moore, T.; Hetts, S. W.; Grubbs, R. H.
Nature Communications 2018, 9 (1).

140. Metathesis and Decomposition of Fischer Carbenes of Cyclometalated Z-Selective Ruthenium Metathesis Catalysts
Ahmed, T. S.; Grandner, J. M.; Taylor, B. L. H.; Herbert, M. B.; Houk, K. N.; Grubbs, R. H.
Organometallics 2018, 37 (14), 2212–2216.

139. Toward Perfect Regiocontrol for β-Selective Cyclopolymerization Using a Ru-Based Olefin Metathesis Catalyst
Jung, K.; Kim, K.; Sung, J.-C.; Ahmed, T. S.; Hong, S. H.; Grubbs, R. H.; Choi, T.-L.
Macromolecules 2018, 51 (12), 4564–4571.

138. Recent Advances in Ruthenium-Based Olefin Metathesis
Ogba, O.M.; Warner, N. C.; O’Leary, D. J.; Grubbs, R. H.
Chem. Soc. Rev. 2018, 47, 4510–4544.

137. Experimental Formulation of Photonic Crystal Properties for Hierarchically Self-Assembled POSS–Bottlebrush Block Copolymers
Chae, C.-G.; Yu, Y.-G.; Seo, H.-B.; Kim, M.-J.; Grubbs, R. H.; Lee, J.-S.
Macromolecules 2018, 51 (9), 3458–3466.

136. Consequences of Grafting Density on the Linear Viscoelastic Behavior of Graft Polymers
Haugan, I. N.; Maher, M. J.; Chang, A. B.; Lin, T.-P.; Grubbs, R. H.; Hillmyer, M. A.; Bates, F. S.
ACS Macro Letters 2018, 525–530.

135. An Initiation Kinetics Prediction Model Enables Rational Design of Ruthenium Olefin Metathesis Catalysts Bearing Modified Chelating Benzylidenes
Luo, S.-X.; Engle, K. M.; Dong, X.; Hejl, A.; Takase, M. K.; Henling, L. M.; Liu, P.; Houk, K. N.; Grubbs, R. H.
ACS Catalysis 2018, 8 (5), 4600–4611.

134. Disentangling Ligand Effects on Metathesis Catalyst Activity: Experimental and Computational Studies of Ruthenium–Aminophosphine Complexes
Chu, C. K.; Lin, T.-P.; Shao, H.; Liberman-Martin, A. L.; Liu, P.; Grubbs, R. H.
J. Am. Chem. Soc. 2018, 140 (16), 5634–5643.

133. Using Stereoretention for the Synthesis of E-macrocycles with Ruthenium-based Olefin Metathesis Catalysts
Ahmed, T. S.; Montgomery, T. P.; Grubbs, R. H.
Chem. Sci. 2018,9 (14), 3580–3583.

132. Design, Synthesis, and Self-Assembly of Polymers with Tailored Graft Distributions
Chang, A. B.; Lin, T.-P.; Thompson, N. B.; Luo, S.-X.; Liberman-Martin, A. L.; Chen, H.-Y.; Lee, B.; Grubbs, R. H.
J. Am. Chem. Soc. 2017.

131. Effects of Grafting Density on Block Polymer Self-Assembly: From Linear to Bottlebrush
Lin, T.-P.; Chang, A. B.; Luo, S.-X.; Chen, H.-Y.; Lee, B.; Grubbs, R. H.
ACS Nano 2017.

130. Catalytic Reduction of Alkyl and Aryl Bromides Using Propan-2-ol
Haibach, M. C.; Stoltz, B. M.; Grubbs, R. H.
Angewandte Chemie International Edition 2017.

129. Ruthenium Olefin Metathesis Catalysts Featuring a Labile Carbodicarbene Ligand
Liberman-Martin, A. L.; Grubbs, R. H.
Organometallics 2017.

128. Electrochemistry in Ionic Liquids: Case Study of a Manganese Corrole
Mcnicholas, B. J.; Blumenfeld, C.; Kramer, W. W.; Grubbs, R. H.; Winkler, J. R.; Gray, H. B.
Russian Journal of Electrochemistry 2017, 53 (10), 1189–1193.

127. Synthesis and Evaluation of Sterically Demanding Ruthenium Dithiolate Catalysts for Stereoretentive Olefin Metathesis
Montgomery, T. P.; Grandner, J. M.; Houk, K. N.; Grubbs, R. H.
Organometallics 2017, 36 (20), 3940–3953.

126. Origins of the Stereoretentive Mechanism of Olefin Metathesis with Ru-Dithiolate Catalysts
Grandner, J. M.; Shao, H.; Grubbs, R. H.; Liu, P.; Houk, K. N.
The Journal of Organic Chemistry 2017, 82 (19), 10595–10600.

125. Stereoretentive Olefin Metathesis: An Avenue to Kinetic Selectivity
Montgomery, T. P.; Ahmed, T. S.; Grubbs, R. H.
Angewandte Chemie International Edition 2017, 56, 2–15.

124. A Highly Efficient Synthesis of Z-Macrocycles Using Stereoretentive, Ruthenium-Based Metathesis Catalysts
Ahmed, T. S.; Grubbs, R. H.
Angewandte Chemie International Edition 2017, 129, 1–5.

123. Application of Bottlebrush Block Copolymers as Photonic Crystals
Liberman-Martin, A. L.;Chu, C. K.; Grubbs, R. H.
Macromolecular Rapid Communications 2017, 38, 1700058.

122. Manipulating the ABCs of Self-Assembly via Low-χ Block Polymer Design
Chang, A. B.; Bates, C. M.; Lee, B.; Garland, C. M.; Jones, S. C.; Spencer, R. K. W.; Matsen, M. W.; Grubbs, R. H.
Proceedings of the National Academy of Sciences 2017, 1701386114.

121. Recent Advancements in Stereoselective Olefin Metathesis Using Ruthenium Catalysts
Montgomery, T. P.; Johns, A. M.; Grubbs, R. H.
Catalysts 2017, 139(7), 87.

120. Control of Grafting Density and Distribution in Graft Polymers by Living Ring-Opening Metathesis Copolymerization
Lin, T.-P.; Chang, A. B.; Chen, H.-Y.; Liberman-Martin, A. L.; Bates, C. M.; Voegtle, M. J.; Bauer, C. A.; Grubbs, R. H.
J. Am. Chem. Soc. 2017, 139, 3896–3903.

119. Functionalized 3D Architected Materials via Thiol-Michael Addition and Two-Photon Lithography
Yee, D. W.; Schulz, M. D.; Grubbs, R. H.; Greer, J. R.
Advanced Materials 2017, 1605293.

118. Fast-Initiating, Ruthenium-based Catalysts for Improved Activity in Highly E-Selective Cross Metathesis
Ahmed, T. S.; Grubbs, R. H.
J. Am. Chem. Soc. 2017, 139, 1532–1537.

117. A potassium tert-butoxide and hydrosilane system for ultra-deep desulfurization of fuels
Toutov, A. A.; Salata, M.; Fedorov, A.; Yang, Y.-F.; Liang, Y.; Cariou, R.; Betz, K. N.; Couzijn, E. P. A.; Shabaker, J. W.; Houk, K. N.; Grubbs, R. H.
Nature Energy 2017, 2, 1–7.

116. Alkali Metal Hydroxide–Catalyzed C(sp)–H Bond Silylation
Toutov, A. A.; Betz, K. N.; Schuman, D. P.; Liu, W.-B.; Fedorov, A.; Stoltz, B. M.; Grubbs, R. H.
J. Am. Chem. Soc. 2017, 139, 1668–1674.

115. Sodium Hydroxide Catalyzed Dehydrocoupling of Alcohols with Hydrosilanes
Toutov, A. A.; Betz, K. N.; Haibach, M. C.; Romine, A. M.; Grubbs, R. H.
Org. Lett. 2016, 18, 5776–5779.

114. Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate
Li, J.; Grubbs, R. H.; Stoltz, B. M.
Org. Lett. 2016, 18, 5449–5451.

113. Synthesis and Catalytic Activity of Supported Acenaphthoimidazolylidene N-Heterocyclic Carbene Ruthenium Complex for Ring Closing Metathesis (RCM) and Ring Opening Metathesis Polymerization (ROMP)
Hill, A. R.; Monchoa, S.; Tuba, R.; Elsaidc, K.; Szarkab, G.; Brothers, E. N.; Grubbs, R. H.; Al-Hashimia, M.; Bazzi, H. S.
J. Catal. 2016, 344, 100–107.

112. Z-Selective Cross-Metathesis and Homodimerization of 3E-1,3-Dienes: Reaction Optimization, Computational Analysis, and Synthetic Applications
Luo, S.-X.; Cannon, J. S.; Taylor, B. H. L.; Engle, K. M.; Houk, K. N.; Grubbs, R. H.
J. Am. Chem. Soc. 2016, 138, 14039–14046.

111. Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation
Kim, K. E.; Li, J.; Grubbs, R. H.; Stoltz, B. M.
J. Am. Chem. Soc. 2016, 138, 13179–13182.

110. Electrocatalysis of CO2 Reduction in Brush Polymer Ion Gels
McNicholas, B. J.; Blakemore, J. D; Chang, A. B; Bates, C.; Kramer, W.; Grubbs, R. H; Gray, H. B.
J. Am. Chem. Soc. 2016, 138, 11160–11163.

109. Direct Access to β-Fluorinated Aldehydes by Nitrite-Modified Wacker Oxidation
Chu, C. K.; Ziegler, D. T.; Carr, B.; Wickens, Z. K.; Grubbs, R. H.
Angew. Chem., Int. Ed. 2016, 55, 8435-8439.

108. Validation of Sensor for Postoperative Positioning with Intraocular Gas
Brodie, F. L; Woo, K. Y; Balakrishna, A.; Choo, H.; Grubbs, R. H.
Clin. Ophthalmol. 2016, 10, 955-960.

107. In Situ Catalyst Modification in Atom Transfer Radical Reactions with Ruthenium Benzylidene Complexes
Lee, J.; Grandner, J. M.; Engle, K. M.; Houk, K. N.; Grubbs, R. H.
J. Am. Chem. Soc. 2016, 138, 7171-7177.

106. Tandem Olefin Metathesis/Oxidative Cyclization: Synthesis of Tetrahydrofuran Diols from Simple Olefins
Dornan, P. K.; Grubbs, R. H.
J. Am. Chem. Soc. 2016, 138, 6372-6375.

105. Cellular Uptake and Anticancer Activity of Carboxylated Gallium Corroles
Pribisko, M.; Palmer, J.; Grubbs, R. H.; Gray, H. B.; Termini, J.; Lim, P.
Proc. Natl. Acad. Sci. U. S. A. 2016, 113, E2258-2266.

104. A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand
Martin, D.; Marx, V. M.; Grubbs, R. H.; Bertrand, G.
Adv. Synth. Catal. 2016, 358, 965-969.

103. High Trans Kinetic Selectivity in Ruthenium-Based Olefin Cross-Metathesis through Stereoretention
Johns, A. M.; Ahmed, T. S.; Jackson, B. W.; Grubbs, R. H.; Pederson, R. L.
Org. Lett. 2016, 18, 772-775.

102. Cationic Ruthenium Alkylidene Catalysts Bearing Phosphine Ligands
Endo, K.; Grubbs, R. H.
Dalton Trans. 2016, 45, 3627-3634.

101. Probing Stereoselectivity in Ring-Opening Metathesis Polymerization Mediated by Cyclometalated Ruthenium-Based Catalysts: A Combined Experimental and Computational Study
Rosebrugh, L. E.; Ahmed, T. S.; Marx, V. M.; Hartung, J.; Liu, P.; López, J. G.; Houk, K. N.; Grubbs, R. H.
J. Am. Chem. Soc. 2016, 138, 1394-1405.

100. Synthesis of Polypentenamer and Poly(Vinyl Alcohol) with a Phase-Separable Polyisobutylene-Supported Second-Generation Hoveyda-Grubbs Catalyst
Al-Hashimi, M.; Tuba, R.; Bazzi, H. S.; Grubbs, R. H.
ChemCatChem 2016, 8, 228-233.

99. Brush Polymer Ion Gels
Bates, C. M.; Chang, A. B.; Schulze, M. W.; Momčilovič, N.; Jones, S. C.; Grubbs, R. H.
J. Polym. Sci. Part B Polym. Phys. 2016, 54, 292-300.

98. Catalytic C-H Bond Silylation of Aromatic Heterocycles
Toutov, A. A.; Liu, W.-B.; Betz, K. N.; Stoltz, B. M.; Grubbs, R. H.
Nat. Protoc. 2015, 10, 1897-1903.

97. Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (-)-Aspewentins A, B, and C
Liu, Y.; Virgil, S. C.; Grubbs, R. H.; Stoltz, B. M.
Angew. Chem., Int. Ed. 2015, 54, 11800-11803.

96. Multiple Olefin Metathesis Polymerization That Combines All Three Olefin Metathesis Transformations: Ring-Opening, Ring-Closing, and Cross Metathesis
Lee, H.-K.; Bang, K.-T.; Hess, A.; Grubbs, R. H.; Choi, T.-L.
J. Am. Chem. Soc. 2015, 137, 9262-9265.

95. ABA Triblock Brush Polymers: Synthesis, Self-Assembly, Conductivity, and Rheological Properties
Bates, C. M.; Chang, A. B.; Momćilović, N.; Jones, S. C.; Grubbs, R. H.
Macromolecules 2015, 48, 4967-4973.

94. Cyclometalated Z-Selective Ruthenium Metathesis Catalysts with Modified N-Chelating Groups
Herbert, M. B.; Suslick, B. A.; Liu, P.; Zou, L.; Dornan, P. K.; Houk, K. N.; Grubbs, R. H.
Organometallics 2015, 34, 2858-2869.

93. Thermomechanical Behavior and Local Dynamics of Dendronized Block Copolymers and Constituent Homopolymers
Aluculesei, A.; Pipertzis, A.; Piunova, V. A.; Miyake, G. M.; Floudas, G.; Fytas, G.; Grubbs, R. H.
Macromolecules 2015, 48, 4142-4150.

92. Stereoselective Synthesis of Macrocyclic Peptides via a Dual Olefin Metathesis and Ethenolysis Approach
Mangold, S. L.; Grubbs, R. H.
Chem. Sci. 2015, 6, 4561-4569.

91. Tandem Z-Selective Cross-Metathesis/Dihydroxylation: Synthesis of anti-1,2-Diols
Dornan, P. K.; Wickens, Z. K.; Grubbs, R. H.
Angew. Chem., Int. Ed. 2015, 54, 7134-7138.

90. Origins of Initiation Rate Differences in Ruthenium Olefin Metathesis Catalysts Containing Chelating Benzylidenes
Engle, K. M.; Lu, G.; Luo, S.-X.; Henling, L. M.; Takase, M. K.; Liu, P.; Houk, K. N.; Grubbs, R. H.
J. Am. Chem. Soc. 2015, 137, 5782-5792.

89. Synthesis of Substituted Dihydrobenzofurans via Tandem SNAr/5-Exo-Trig Cyclization
Koy, M.; Engle, K. M.; Henling, L. M.; Takase, M. K.; Grubbs, R. H.
Org. Lett. 2015, 17, 1986-1989.

88. Control of Oligomerization and Oxidation Steps in the Synthesis of Tris(pentafluorophenyl)corrole
Blumenfeld, C.; Fisher, K. J.; Henling, L. M.; Grubbs, R. H.; Gray, H. B.; Virgil, S. C.
Eur. J. Org. Chem. 2015, 14, 3022-3025.

87. An SNAr Approach to Sterically Hindered ortho-Alkoxybenzaldehydes for the Synthesis of Olefin Metathesis Catalysts
Engle, K. M.; Luo, S.-X.; Grubbs, R. H.
J. Org. Chem. 2015, 80, 4213-4220.

86. The Linear Rheological Responses of Wedge-Type Polymers
Hu, M.; Xia, Y.; Daeffler, C. S.; Wang, J.; McKenna, G. B.; Kornfield, J. A.; Grubbs, R. H.
J. Polym. Sci. Part B Polym. Phys. 2015, 53, 899-906.

85. Z-Selective Cross Metathesis with Ruthenium Catalysts: Synthetic Applications and Mechanistic Implications
Herbert, M. B.; Grubbs, R. H.
Angew. Chem., Int. Ed. 2015, 54, 5018-5024.

84. An In Vitro Enzymatic Assay to Measure Transcription Inhibition by Gallium(III) and H3 5,10,15-Tris(pentafluorophenyl)corroles
Tang, G. Y.; Pribisko, M. A.; Henning, R. K.; Lim, P.; Termini, J.; Gray, H. B.; Grubbs, R. H.
J. Vis. Exp. 2015, 97, e52355/1-e52355/8.

83. Targeted Microbubbles: a Novel Application for the Treatment of Kidney Stones
Ramaswamy, K.; Chi, T.; Stoller, M. L.; Marx, V. M.; Grubbs, R. H,; Laser, D.; Kenny, T.; Bailey, M.; Sorensen, M. D.
BJU Int. 2015, 116, 9-16.

82. Silylation of C-H bonds in Aromatic Heterocycles by an Earth-Abundant Metal Catalyst
Toutov, A. A.; Liu, W.-B.; Betz, K. N.; Fedorov, A.; Stoltz, B. M.; Grubbs, R. H.
Nature 2015, 518, 80-84.

81. Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis
Marx, V. M.; Sullivan, A. H.; Melaimi, M.; Virgil, S. C.; Keitz, B. K.; Weinberger, D. S.; Bertrand, G.; Grubbs, R. H.
Angew. Chem., Int. Ed. 2015, 54, 1919-1923.

80. Aerobic Palladium-Catalyzed Dioxygenation of Alkenes Enabled by Catalytic Nitrite
Wickens, Z. K.; Guzman, P. E.; Grubbs, R. H.
Angew. Chem., Int. Ed. 2015, 54, 236-240.

79. Cyclometalated Ruthenium Alkylidene Complexes: A Powerful Family of Z-Selective Olefin Metathesis Catalysts
Marx, V. M.; Rosebrugh, L. E.; Herbert, M. B.; Grubbs, R. H.
Top. Organomet. Chem. 2015, 48, 1-17.

78. Z-Selective Ruthenium Metathesis Catalysts: Comparison of Nitrate and Nitrite X-type Ligands
Pribisko, M. A.; Ahmed, T. S.; Grubbs, R. H.
Polyhedron 201484, 144-149.

77. One-Pot Synthesis of Poly(vinyl alcohol) (PVA) Copolymers via Ruthenium Catalyzed Equilibrium Ring-Opening Metathesis Polymerization of Hydroxyl Functionalized Cyclopentene
Tuba, R.; Al-Hashimi, M.; Bazzi, H. S.; Grubbs, R. H.
Macromolecules 201447, 8190-8195.

76. Improving Brush Polymer Infrared One-Dimensional Photonic Crystals via Linear Polymer Additives
Macfarlane, R. J.; Kim, B.; Lee, B.; Weitekamp, R. A.; Bates, C. M.; Lee, S. F.; Chang, A. B.; Delaney, K. T.; Fredrickson, G. H.; Atwater, H. A.; Grubbs, R. H.
J. Am. Chem. Soc. 2014136, 17374-17377.

75. Cellular Uptake and Cytotoxicity of a near-IR Fluorescent Corrole-TiO2 Nanoconjugate
Blumenfeld, C. M., Sadtler, B. F., Fernandez, G. E., Dara, L., Nguyen, C., Alonso-Valenteen, F., Medina-Kauwe, L., Moats, R. A., Lewis, N. S., Grubbs, R. H., Gray, H. B., Sorasaenee, K.
J. Inorg. Biochem. 2014140, 39-44.

74. Sequence-Controlled Polymers by Ruthenium-Mediated Ring-Opening Metathesis Polymerization
Chang, A. B.; Miyake, G. M.; Grubbs, R. H.
ACS Symp. Ser. 20141170, 161-188.

73. Enantioselective Olefin Metathesis with Cyclometalated Ruthenium Complexes
Hartung, J.; Dornan, P. K.; Grubbs, R. H.
J. Am. Chem. Soc. 2014136, 13029-13037.

72. Z-Selective Olefin Metathesis on Peptides: Investigation of Side-Chain Influence, Preorganization, and Guidelines in Substrate Selection
Mangold, S. L.; O’Leary, D. J.; Grubbs, R. H.
J. Am. Chem. Soc. 2014136, 12469-12478.

71. Rapid Access to β-Trifluoromethyl-Substituted Ketones. Harnessing Inductive Effects in Wacker-Type Oxidations of Internal Alkenes
Lerch, M. M.; Morandi, B.; Wickens, Z. K.; Grubbs, R. H.
Angew. Chem., Int. Ed. 201453, 8654-8658.

70. Ru-Based Z-Selective Metathesis Catalysts with Modified Cyclometalated Carbene Ligands
Bronner, S. M.; Herbert, M. B.; Patel, P. R.; Marx, V. M.; Grubbs, R. H.
Chem. Sci. 20145, 4091-4098.

69. Carboxylate-Assisted C(sp3)-H Activation in Olefin Metathesis-Relevant Ruthenium Complexes
Cannon, J. S.; Zou, L.; Liu, P.; Lan, Y.; O’Leary, D. J.; Houk, K. N.; Grubbs, R. H.
J. Am. Chem. Soc. 2014136, 6733-6743.

68. Catalytic, Enantioselective Synthesis of 1,2-anti-Diols by Asymmetric Ring-Opening/Cross-Metathesis
Hartung, J.; Grubbs, R. H.
Angew. Chem., Int. Ed. 201453, 3885-3888.

67. Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins
Liu, Y.; Kim, K. E.; Herbert, M. B.; Fedorov, A.; Grubbs, R. H.; Stoltz, B. M.
Adv. Synth. Catal. 2014356, 130-136.

66. Catalyst-Controlled Wacker-Type Oxidation: Facile Access to Functionalized Aldehydes
Wickens, Z. K.; Skakuj, K.; Morandi, B.; Grubbs, R. H.
J. Am. Chem. Soc. 2014136, 890-893.

65. Partial Kinetic Resolution of Oxanorbornenes by Ring-Opening Metathesis Polymerization with a Chiral Ruthenium Initiator
Daeffler, C. S.; Miyake, G. M.; Li, J.; Grubbs, R. H.
ACS Macro Lett. 20143, 102-104.

64. Z-Selective Olefin Metathesis Catalysts and Their Applications
Endo, K.; Grubbs, R. H.
Kobunshi 201463, 176-177.

63. Stereocomplex Formation of Densely Grafted Brush Polymers
Sveinbjörnsson, B. R.; Miyake, G. M.; El-Batta, A.; Grubbs, R. H.
ACS Macro Lett. 20143, 26-29.

62. Ruthenium-Catalysed Z-Selective Cross Metathesis of Allylic-Substituted Olefins
Quigley, B. L.; Grubbs, R. H.
Chem. Sci. 20145, 501-506.

61. Formal anti-Markovnikov Hydroamination of Terminal Olefins
Bronner, S. M.; Grubbs, R. H.
Chem. Sci. 20145, 101-106.

60. Photolithographic Olefin Metathesis Polymerization
Weitekamp, R. A.; Atwater, H. A.; Grubbs, R. H.
J. Am. Chem. Soc. 2013135, 16817-16820.

59. On the Self-Assembly of Brush Block Copolymers in Thin Films
Hong, S. W.; Gu, W.; Huh, J.; Sveinbjörnsson, B. R.; Jeong, G.; Grubbs, R. H.; Russell, T. P.
ACS Nano 20137, 9684-9692.

58. On the Self-Assembly of Brush Block Copolymers in Thin Films
Hong, S. W.; Gu, W.; Huh, J.; Sveinbjörnsson, B. R.; Jeong, G.; Grubbs, R. H.; Russell, T. P.
ACS Nano 20137, 9684-9692.

57. Highly Ordered Dielectric Mirrors via the Self-Assembly of Dendronized Block Copolymers
Piunova, V. A.; Miyake, G. M.; Daeffler, C. S.; Weitekamp, R. A.; Grubbs, R. H.
J. Am. Chem. Soc. 2013135, 15609-15616.

56. Aldehyde-Selective Wacker-Type Oxidation of Unbiased Alkenes Enabled by a Nitrite Co-Catalyst
Wickens, Z. K.; Morandi, B.; Grubbs, R. H.
Angew. Chem., Int. Ed. 201352, 11257-11260.

55. Investigations into Ruthenium Metathesis Catalysts with Six-Membered Chelating NHC Ligands: Relationship between Catalyst Structure and Stereoselectivity
Endo, K.; Herbert, M. B.; Grubbs, R. H.
Organometallics 201332, 5128-5135.

54. Regioselective Wacker Oxidation of Internal Alkenes: Rapid Access to Functionalized Ketones Facilitated by Cross-Metathesis
Morandi, B.; Wickens, Z. K.; Grubbs, R. H.
Angew. Chem., Int. Ed. 201352, 9751-9754.

53. Confined Organization of Fullerene Units along High Polymer Chains
Fang, L.; Liu, P.; Sveinbjörnsson, B. R.; Atahan-Evrenk, S.; Vandewal, K.; Osuna, S.; Jimenez-Oses, G.; Shrestha, S.; Giri, G.; Wei, P.; Salleo, A.; Aspuru-Guzik, A.; Grubbs, R. H.; Houk, K. N.; Bao, Z.
J. Mater. Chem. C 20131, 5747-5755.

52. Alkene Chemoselectivity in Ruthenium-Catalyzed Z-Selective Olefin Metathesis
Cannon, J. S.; Grubbs, R. H.
Angew. Chem., Int. Ed. 201352, 9001-9004.

51. Highly Z-Selective and Enantioselective Ring-Opening/Cross-Metathesis Catalyzed by a Resolved Stereogenic-at-Ru Complex
Hartung, J.; Grubbs, R. H.
J. Am. Chem. Soc. 2013135, 10183-10185.

50. Synthesis of Highly Cis, Syndiotactic Polymers via Ring-Opening Metathesis Polymerization Using Ruthenium Metathesis Catalysts
Rosebrugh, L. E.; Marx, V. M.; Keitz, B. K.; Grubbs, R. H.
J. Am. Chem. Soc. 2013135, 10032-10035.

49. Ruthenium Catalyzed Equilibrium Ring-Opening Metathesis Polymerization of Cyclopentene
Tuba, R.; Grubbs, R. H.
Polym. Chem. 20134, 3959-3962.

48. Decorating Metal Oxide Surfaces with Fluorescent Chlorosulfonated Corroles
Blumenfeld, C. M.; Grubbs, R. H.; Moats, R. A.; Gray, H. B.; Sorasaenee, K.
Inorg. Chem. 201352, 4774-4776.

47. Catalyst-Dependent Routes to Ring-Opening Metathesis Alternating Copolymers of Substituted Oxanorbornenes and Cyclooctene
Daeffler, C. S.; Grubbs, R. H.
Macromolecules 201346, 3288-3292.

46. Z-Selective Ethenolysis with a Ruthenium Metathesis Catalyst: Experiment and Theory
Miyazaki, H.; Herbert, M. B.; Liu, P.; Dong, X.; Xu, X.; Keitz, B. K.; Ung, T.; Mkrtumyan, G.; Houk, K. N.; Grubbs, R. H.
J. Am. Chem. Soc. 2013135, 5848-5858.

45. Chelating N-Heterocyclic Carbene Group IV Complexes for the Polymerization of Ethylene and Styrene
Miyake, G. M.; Akhtar, M. N.; Fazal, A.; Jaseer, E. A.; Daeffler, C. S.; Grubbs, R. H.
J. Organomet. Chem. 2013728, 1-5.

44. Light-Triggered Modulation of Cellular Electrical Activity by Ruthenium Diimine Nanoswitches
Rohan, J. G.; Citron, Y. R.; Durrell, A. C.; Cheruzel, L. E.; Gray, H. B.; Grubbs, R. H.; Humayun, M.; Engisch, K. L.; Pikov, V.; Chow, R. H.
ACS Chem. Neurosci. 20134, 585-593.

43. Lewis-Base Silane Activation: From Reductive Cleavage of Aryl Ethers to Selective ortho-Silylation
Fedorov, A.; Toutov, A. A.; Swisher, N. A.; Grubbs, R. H.
Chem. Sci. 20134, 1640-1645.

42. Self-Assembly of Symmetric Brush Diblock Copolymers
Gu, W.; Huh, J.; Hong, S. W.; Sveinbjörnsson, B. R.; Park, C.; Grubbs, R. H.; Russell, T. P.
ACS Nano 20137, 2551-2558.

41. Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins
Morandi, B.; Wickens, Z. K.; Grubbs, R. H.
Angew. Chem., Int. Ed. 201352, 2944-2948.

40. Highly Active Ruthenium Metathesis Catalysts Exhibiting Unprecedented Activity and Z-Selectivity
Rosebrugh, L. E.; Herbert, M. B.; Marx, V. M.; Keitz, B. K.; Grubbs, R. H.
J. Am. Chem. Soc. 2013135, 1276-1279.

39. Stereoselective Access to Z and E Macrocycles by Ruthenium-Catalyzed Z-Selective Ring-Closing Metathesis and Ethenolysis
Marx, V. M.; Herbert, M. B.; Keitz, B. K.; Grubbs, R. H.
J. Am. Chem. Soc. 2013135, 94-97.

38. Solar Cell Efficiency Enhancement via Light Trapping in Printable Resonant Dielectric Nanosphere Arrays
Grandidier, J.; Weitekamp, R. A.; Deceglie, M. G.; Callahan, D. M.; Battaglia, C.; Bukowsky, C. R.; Ballif, C.; Grubbs, R. H.; Atwater, H. A.
Phys. Status Solidi A 2013210, 255-260.

37. Concise Syntheses of Insect Pheromones Using Z-Selective Cross Metathesis
Herbert, M. B.; Marx, V. M.; Pederson, R. L.; Grubbs, R. H.
Angew. Chem., Int. Ed. 201352, 310-314.

36. Electron Transfer Triggered by Optical Excitation of Phenothiazine-tris(meta-phenylene-ethynylene)-(tricarbonyl)(bpy)(py)rhenium(I)
Bingöl, B.; Durrell, A. C.; Keller, G. E.; Palmer, J. H.; Grubbs, R. H.; Gray, H. B.
J. Phys. Chem. B 2013117, 4177-4182.

35. Rapidly Cross-Linkable DOPA Containing Terpolymer Adhesives and PEG-Based Cross-Linkers for Biomedical Applications
Chung, H.; Grubbs, R. H.
Macromolecules 201245, 9666-9673.

34. Application of 1H DOSY for Facile Measurement of Polymer Molecular Weights
Li, W.; Chung, H.; Daeffler, C.; Johnson, J. A.; Grubbs, R. H.
Macromolecules 201245, 9595-9603.

33. Using EPR To Compare PEG-Branch-Nitroxide “Bivalent-Brush Polymers” and Traditional PEG Bottle-Brush Polymers: Branching Makes a Difference
Burts, A. O.; Li, Y.; Zhukhovitskiy, A. V.; Patel, P. R.; Grubbs, R. H.; Ottaviani, M. F.; Turro, N. J.; Johnson, J. A.
Macromolecules 2012, 45, 8310-8318.

32. Precisely Tunable Photonic Crystals From Rapidly Self-Assembling Brush Block Copolymer Blends
Miyake, G. M.; Piunova, V. A.; Weitekamp, R. A.; Grubbs, R. H.
Angew. Chem., Int. Ed. 201251, 11246-11248.

31. Synthesis of Isocyanate-Based Brush Block Copolymers and Their Rapid Self-Assembly to Infrared-Reflecting Photonic Crystals
Miyake, G. M.; Weitekamp, R. A.; Piunova, V. A.; Grubbs, R. H.
J. Am. Chem. Soc. 2012, 134, 14249-14254.

30. Rapid Self-Assembly of Brush Block Copolymers to Photonic Crystals
Sveinbjöernsson, B. R.; Weitekamp, R. A.; Miyake, G. M.; Xia, Y.; Atwater, H. A.; Grubbs, R. H.
Proc. Natl. Acad. Sci. U.S.A. 2012109, 14332-14336.

29. Synthesis and Cell Adhesive Properties of Linear and Cyclic RGD Functionalized Polynorbornene Thin Films
Patel, P. R.; Kiser, R. C.; Lu, Y. Y.; Fong, E.; Ho, W. C.; Tirrell, D. A.; Grubbs, R. H.
Biomacromolecules 2012, 13, 2546-2553.

28. Efficient and Highly Aldehyde Selective Wacker Oxidation
Teo, P.; Wickens, Z. K.; Dong, G.; Grubbs, R. H.
Org. Lett. 201214, 3237-3239.

27. Cross Metathesis Assisted Solid-Phase Synthesis of Glycopeptoids
Khan, S. N.; Kim, A.; Grubbs, R. H.; Kwon, Y.-U.
Org. Lett. 201214, 2952-2955.

26. Decomposition Pathways of Z-Selective Ruthenium Metathesis Catalysts
Herbert, M. B.; Lan, Y.; Keitz, B. K.; Liu, P.; Endo, K.; Day, M. W.; Houk, K. N.; Grubbs, R. H.
J. Am. Chem. Soc. 2012134, 7861-7866.

25. Cis-Selective Ring-Opening Metathesis Polymerization with Ruthenium Catalysts
Keitz, B. K.; Fedorov, A.; Grubbs, R. H.
J. Am. Chem. Soc. 2012134, 2040-2043.

24. Z-Selectivity in Olefin Metathesis with Chelated Ru Catalysts: Computational Studies of Mechanism and Selectivity
Liu, P.; Xu, X.; Dong, X.; Keitz, B. K.; Herbert, M. B.; Grubbs, R. H.; H., K. N.
J. Am. Chem. Soc. 2012, 134, 1464-1467.

23. H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex
Iluc, V. M.; Fedorov, A.; Grubbs, R. H.
Organometallics 201231, 39-41.

22. Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis
Keitz, B. K.; Endo, K.; Patel, P. R.; Herbert, M. B.; Grubbs, R. H.
J. Am. Chem. Soc. 2012134, 693-699.

21. Discussion Addendum for: Ring-Closing Metathesis Synthesis of N-Boc-3-pyrroline
O’Leary, D. J.; Pederson, R.; Grubbs, R. H.
Org. Synth. 201289, 170-182.

20. Insights into the Carbene-Initiated Aggregation of [Fe(cot)2]
Lavallo, V.; El-Batta, A.; Bertrand, G.; Grubbs, R. H.
Angew. Chem., Int. Ed. 2011, 50, 268-271.

19. Radical-Mediated Anti-Markovnikov Hydrophosphonation of Olefins
Daeffler, C. S.; Grubbs, R. H.
Org. Lett. 2011, 13, 6429-6431.

18. Thermally Stable, Latent Olefin Metathesis Catalysts
Thomas, R. M.; Fedorov, A.; Keitz, B. K.; Grubbs, R. H.
Organometallics 2011, 30, 6713-6717.

17. EPR Study of Spin Labeled Brush Polymers in Organic Solvents
Xia, Y.; Li, Y.; Burts, A. O.; Ottaviani, M. F.; Tirrell, D. A.; Johnson, J. A.; Turro, N. J.; Grubbs, R. H.
J. Am. Chem. Soc. 2011, 133, 19953-19959.

16. One-Pot Synthesis of Polyrotaxanes via Acyclic Diene Metathesis Polymerization of Supramolecular Monomers
Momcilovic, N.; Clark, P. G.; Boydston, A. J.; Grubbs, R. H.
J. Am. Chem. Soc. 2011, 133, 19087-19089.

15. Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration via Triple Relay Catalysis
Dong, G.; Teo, P.; Wickens, Z. K.; Grubbs, R. H.
Science 2011, 333, 1609-1612.

14. Probing the Origin of Degenerate Metathesis Selectivity via Characterization and Dynamics of Ruthenacyclobutanes Containing Variable NHCs
Keitz, B. K.; Grubbs, R. H.
J. Am. Chem. Soc. 2011, 133, 16277-16284.

13. Linear Rheological Response of a Series of Densely Branched Brush Polymers
Hu, M.; Xia, Y.; McKenna, G. B.; Kornfield, J. A.; Grubbs, R. H.
Macromolecules 2011, 44, 6935-6943.

12. Bis-ligated Ti and Zr complexes of chelating N-heterocyclic carbenes
El-Batta, A.; Waltman, A. W.; Grubbs, R. H.
J. Organomet. Chem. 2011, 696, 2477-2481.

11. Z-Selective Homodimerization of Terminal Olefins with a Ruthenium Metathesis Catalyst
Keitz, B. K.; Endo, K.; Herbert, M. B.; Grubbs, R. H.
J. Am. Chem. Soc. 2011, 133, 9686-9688.

10. Synthesis and Direct Imaging of Ultrahigh Molecular Weight Cyclic Brush Polymers
Xia, Y.; Boydston, A. J.; Grubbs, R. H.
Angew. Chem., Int. Ed. 2011, 50, 5882-5885.

9. Protonolysis of a Ruthenium-Carbene Bond and Applications in Olefin Metathesis
Keitz, B. K.; Bouffard, J.; Bertrand, G.; Grubbs, R. H.
J. Am. Chem. Soc. 2011, 133, 8498-8501.

8. Chelated Ruthenium Catalysts for Z-Selective Olefin Metathesis
Endo, K.; Grubbs, R. H.
J. Am. Chem. Soc. 2011, 133, 8525-8527.

7. Highly Selective Ruthenium Metathesis Catalysts for Ethenolysis
Thomas, R. M.; Keitz, B. K.; Champagne, T. M.; Grubbs, R. H.
J. Am. Chem. Soc. 2011, 133, 7490-7496.

6. Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and Their Applications in Ruthenium-Catalyzed Olefin Metathesis
Bouffard, J.; Keitz, B. K.; Tonner, R.; Guisado-Barrios, G.; Frenking, G.; Grubbs, R. H.; Bertrand, G.
Organometallics 2011, 30, 2617-2627.

5. Low Pressure Ethenolysis of Renewable Methyl Oleate in a Microchemical System
Park, C. P.; Van Wingerden, M. M.; Han, S.-Y.; Kim, D.-P.; Grubbs, R. H.
Org. Lett. 2011, 13, 2398-2401.

4. Mechanistic Studies of Enantioselective N-Aryl, N-Alkyl N-Heterocyclic Carbene (NHC) Ruthenium Metathesis Catalysts in Asymmetric Ring-Opening Cross-Metathesis (AROCM)
Thomas, R. M.; Grubbs, R. H.
Chem. New Zealand 2011, 75, 65-71.

3. Characterization and Dynamics of Substituted Ruthenacyclobutanes Relevant to the Olefin Cross-Metathesis Reaction
Wenzel, A. G.; Blake, G.; VanderVelde, D. G.; Grubbs, R. H.
J. Am. Chem. Soc. 2011, 133, 6429-6439.

2. Ring-Closing Metathesis Approaches for the Solid-Phase Synthesis of Cyclic Peptoids
Khan, S. N.; Kim, A.; Grubbs, R. H.; Kwon, Y.-U.
Org. Lett. 2011, 13, 1582-1585.

1. Core-Clickable PEG-Branch-Azide Bivalent-Bottle-Brush Polymers by ROMP: Grafting-Through and Clicking-To
Johnson, J. A.; Lu, Y.-Y.; Burts, A. O.; Lim, Y.-H.; Finn, M. G.; Koberstein, J. T.; Turro, N. J.; Tirrell, D. A.; Grubbs, R. H.
J. Am. Chem. Soc. 2011, 133, 559-566.